Ligandy na bázi cínu v chemii prvků 11. skupiny – Bc. Jitka Raisová

Anotace:

V ramci teto diplomove prace byla vypracovana re.er.e na tema chemie tetrylen. s prvky 11. skupiny. Tato re.er.e prokazala schopnost tetrylen. koordinovat prvky 11. skupiny. V ramci experimentalni .asti byly p.ipraveny slou.eniny LSnCl (I), LSn(C?ßCPh) (II), LSn(C?ßCSiMe3) (III) a LSn(C?ßCCH2NMe2) (IV) (kde L= 2,6-bis[(dimethylamino)methyl]fenyl), u nich. byla zkoumana reaktivita s prvky 11. skupiny. Reakcemi slou.enin I-IV s MI solemi (M= Cu, Ag, Au) byly p.ipraveny slou.eniny V-X. V.echny nov. p.ipravene slou.eniny byly analyzovany pomoci NMR spektroskopie, ESI-MS hmotnostni spektrometrie a rentgenove difrak.ni analyzy. …víceméně

Abstract:

As part of this Diploma work was written out a literature review on the theme of chemistry of tetrylenes with elements of the 11th group. This research demonstrated the ability of tetrylenes to coordinate the elements of the 11th group. In the experimental part, have been prepared compounds LSnCl (I), LSn(C?ßCPh) (II), LSn(C?ßCSiMe3) (III) and LSn(C?ßCCH2NMe2) (IV) (where L= 2,6-bis[(dimethylamino)methyl]phenyl), for which reactivity with 11th group elements was investigated. By reactions of compounds I-IV with MI salts (M = Cu, Ag, Au), compounds V-X were prepared. All newly prepared compounds were analyzed by NMR spectroscopy, ESI-MS mass spectrometry and X-ray diffraction analysis. …víceméně