Intramolekulárně koordinované organokovové chalkogenidy jako SSP pro depozice tenkých vrstev

Ing. Tomáš Řičica

Master's thesis

Intramolecularly coordinated organometallic chalcogenides as SSP for depositions of thin layers

Anotácia:

V ramci teto diplomove prace byly p.ipraveny tenke vrstvy SnS2 a SnS material. pomoci metody rota.niho nana.eni (spin coating) u.itim organocini.iteho polysulfidu [2,6-(Me2NCH2)2C6H3]2Sn2S7, organocinateho sulfidu [({2,6-(Me2NCH2)2C6H3}Sn)2(?Ę-S)] a organocinateho fenylthiolatu {[2,6-(Me2NCH2)2C6H3]SnS(Ph)}. Dale byly p.ipraveny intramolekularn. koordinovane slou.eniny prvk. 12. a 13. skupiny obsahujici neutralni N,N-chelatujici ligand a monoanionicke N,C,N- a C,N-chelatujici ligandy. V.echny p.ipravene slou.eniny byly charakterizovany pomoci 1H, 13C, 77Se a 125Te NMR spektroskopie a molekulove struktury byly potvrzeny pomoci rentgenove difrak.ni analyzy monokrystalickeho materialu.

Abstract:

In the context of this thesis were prepared thin films of SnS2 and SnS materials by method spin coating using organostannane polysulfide [2,6-(Me2NCH2)2C6H3]2Sn2S7, organostannylene sulfide [({2,6-(Me2NCH2)2C6H3}Sn)2(ě-S)] and organostannylene phenylthiolate {[2,6-(Me2NCH2)2C6H3]SnS(Ph)}. Also were prepared intramolecular coordinated compounds of 12. and 13. groups containing N,N-chelating ligand and monoanionic N,C,N- and C,N- chelating ligands All prepared compounds were characterized by 1H, 13C, 77Se and 125Te NMR spectroscopy and the molecular structures were confirmed by X-ray diffraction analysis of monocrystalline material.

Kľúčové slová

spin coating, SSP, organokovové chalkogenidy, chelatující ligandy, tenké vrstvy

Jazyk práce: Czech

Datum vytvoření / odevzdání či podání práce: 9. 5. 2014

Obhajoba závěrečné práce

• Obhajoba proběhla 3. 6. 2014
• Vedúci: doc. Ing. Roman Jambor, Ph.D.

University of Pardubice

Faculty of Chemical Technology

Master programme / odbor:
Chemistry / Inorganic ane Bioinorganic Chemistry