Ligandy na bázi cínu v chemii prvků 11. skupiny

Bc. Jitka Raisová

Master's thesis

Stannylenes as the ligands for group 11th elements

Abstract:

V ramci teto diplomove prace byla vypracovana re.er.e na tema chemie tetrylen. s prvky 11. skupiny. Tato re.er.e prokazala schopnost tetrylen. koordinovat prvky 11. skupiny. V ramci experimentalni .asti byly p.ipraveny slou.eniny LSnCl (I), LSn(C?ßCPh) (II), LSn(C?ßCSiMe3) (III) a LSn(C?ßCCH2NMe2) (IV) (kde L= 2,6-bis[(dimethylamino)methyl]fenyl), u nich. byla zkoumana reaktivita s prvky 11. skupiny. Reakcemi slou.enin I-IV s MI solemi (M= Cu, Ag, Au) byly p.ipraveny slou.eniny V-X. V.echny nov. p.ipravene slou.eniny byly analyzovany pomoci NMR spektroskopie, ESI-MS hmotnostni spektrometrie a rentgenove difrak.ni analyzy.

Abstract:

As part of this Diploma work was written out a literature review on the theme of chemistry of tetrylenes with elements of the 11th group. This research demonstrated the ability of tetrylenes to coordinate the elements of the 11th group. In the experimental part, have been prepared compounds LSnCl (I), LSn(C?ßCPh) (II), LSn(C?ßCSiMe3) (III) and LSn(C?ßCCH2NMe2) (IV) (where L= 2,6-bis[(dimethylamino)methyl]phenyl), for which reactivity with 11th group elements was investigated. By reactions of compounds I-IV with MI salts (M = Cu, Ag, Au), compounds V-X were prepared. All newly prepared compounds were analyzed by NMR spectroscopy, ESI-MS mass spectrometry and X-ray diffraction analysis.

Keywords

tetryleny, prvky 11. skupiny, stannyleny

Language used: Czech

Date on which the thesis was submitted / produced: 10. 5. 2018

Accessible from:: 31. 12. 2999

Thesis defence

• Supervisor: prof. Ing. Roman Jambor, Ph.D.

University of Pardubice

Faculty of Chemical Technology

Master programme / field:
Chemistry / Inorganic ane Bioinorganic Chemistry